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methyl 7-[(3R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-oxocyclopent-1-en-1-yl]heptanoate

methyl (R)-(+)-3-(T-bu-dimethylsilyloxy)-5-oxo-1-

CAS: 41138-69-6

Molecular Formula: C19H34O4Si

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methyl 7-[(3R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-oxocyclopent-1-en-1-yl]heptanoate - Names and Identifiers

Name methyl (R)-(+)-3-(T-bu-dimethylsilyloxy)-5-oxo-1-
Synonyms methyl (R)-(+)-3-(T-bu-dimethylsilyloxy)-5-oxo-1-
METHYL-7-(3-(R)-T-BUTYL DIMETHYLSILOXY-5-OXO-CYCLOPENT-1-ENYL)-HEPTANOATE
METHYL (R)-(+)-3-(TERT-BUTYLDIMETHYLSILYLOXY)-5-OXO-1-CYCLOPENTENE-1-HEPTANOATE
Methyl (R)-(+)-3-(tert-butyldimethylsilyloxy)-5-oxo-1-cyclopentene-1-heptanoate
(R)-Methyl 7-(3-((Tert-Butyldimethylsilyl)Oxy)-5-Oxcyclopent-1-En-1-Yl)Heptanoate
(R)-Methyl 7-(3-((tert-butyldimethylsilyl)-oxy)-5-oxocyclopent-1-en-1-yl)heptanoate
methyl 7-[(3R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-oxocyclopent-1-en-1-yl]heptanoate
7-{3-[(tert-butyldimethylsilanyl)oxy]-5-oxocyclopent-1-en-1-yl}heptanoic acid methyl ester
1-Cyclopentene-1-heptanoic acid,3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-oxo,methyl ester,(3R)-
1-Cyclopentene-1-heptanoic acid,3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-oxo-, methyl ester, (3R)-
CAS 41138-69-6
InChI InChI=1/C19H34O4Si/c1-19(2,3)24(5,6)23-16-13-15(17(20)14-16)11-9-7-8-10-12-18(21)22-4/h13,16H,7-12,14H2,1-6H3/t16-/m0/s1

methyl 7-[(3R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-oxocyclopent-1-en-1-yl]heptanoate - Physico-chemical Properties

Molecular FormulaC19H34O4Si
Molar Mass354.56
Density0.977g/mLat 25°C(lit.)
Boling Point210°C(lit.)
Flash Point41°C
Vapor Presure8.89E-07mmHg at 25°C
Storage Condition2-8°C
Refractive Indexn20/D 1.467(lit.)

methyl 7-[(3R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-oxocyclopent-1-en-1-yl]heptanoate - Risk and Safety

Risk Codes10 - Flammable
Safety Description16 - Keep away from sources of ignition.
UN IDsUN 3272 3/PG 3

methyl 7-[(3R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-oxocyclopent-1-en-1-yl]heptanoate - Introduction

methyl (R)-( )-3-(T-bu-dimethylsilyloxy)-5-oxo-1-is an organic compound. The following is an introduction to the properties, uses, preparation methods and safety information of the compound:

Nature:
-Chemical formula: C16H30O3Si
-Molecular weight: 298.49g/mol
-Appearance: colorless liquid
-Solubility: Soluble in organic solvents

Use:
methyl (R)-( )-3-(T-bu-dimethylsilyloxy)-5-oxo-1-is often used as a reagent in organic synthesis for the synthesis of other organic compounds. It can be used as an intermediate in chiral synthesis for the synthesis of pharmacologically active compounds or for the preparation of chiral catalysts.

Preparation Method:
The preparation of methyl (R)-( )-3-(T-bu-dimethylsilyloxy)-5-oxo-1-can be carried out by the following steps:
1. The heptenoic acid methyl ester reacts with 1,1-dimethylethyl lithium to generate a lithium salt.
2. The lithium salt is reacted with (3R)-3-[[(1,1-dimethylethyl) dimethylsilyl] oxy]-5-oxo-cyclopent-1-ene to generate the target product.

Safety Information:
The use of organic compounds should follow the appropriate safety procedures. This compound may be irritating and volatile, and contact with skin and eyes should be avoided. Wear chemical protective gloves and goggles during operation. If necessary, it should be operated under well-ventilated conditions. If taken by mistake or inhaled by mistake, seek medical attention immediately.
Last Update:2024-04-10 22:29:15
methyl 7-[(3R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-oxocyclopent-1-en-1-yl]heptanoate
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CAS: 41138-69-6
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Shanghai Yuanye Bio-Technology Co., Ltd.
Product Name: METHYL (R)-(+)-3-(TERT-BUTYLDIMETHYLSILYLOXY)-5-OXO-1-CYCLOPENTENE-1-HEPTANOATE Visit Supplier Webpage Request for quotation
CAS: 41138-69-6
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409 Click to send a QQ message
View History
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